Sustainability indicators of water sharing compacts

There is an increasing crisis of fresh water availability throughout the world. Sharing the available water resources in a sustainable manner among numerous stakeholders in the backdrop of this crisis is more challenging. Very often water conflicts are triggered out in this challenging scenario. These conflicts are sometimes reconciled with compacts on sharing. Water sharing compacts on both surface and aquifer resources are very common. Whether these compacts are founded on postulates of sustainability is the important question we want to investigate. Conflicts resurface when the sustainability of a compact is at stake. In this paper, we are reviewing three compacts on surface water sharing to understand their sustainability perspectives and how it has helped addressing conflicts. An introduction to various legal instruments promulgated aiming water conflict abatement is given first. Different types of water sharing agreements being signed in the current water management practice are also looked into. Theoretical background of sustainability analysis, both quantitative and qualitative, applicable in the case of water sharing models is then discussed. This is followed by specific case study analysis of three interstate water sharing agreements executed in basins of different agro-climatic regions across the world. It includes the Colorado basin (USA), Murray Darling basin (Australia) and the Parambikulam Aliyar Project (PAP) basins (India). Interstate water sharing agreement of these basins is critically examined and compared to comment on its sustainability perspective. The Murray Darling basin and its compact appear to be better in its overall considerations of sustainability. Compared to Colorado and Murray Darling, PAP requires major revisions in its sustainability context. E flows and stochastic modeling are the thrust areas of PAP that require major revision.     

Partial characterization of the exopolysaccharide from Oscillatoria trichoides Szafer and the role of released polysaccharide in sequestration of Cr6+

The structural investigation and the chromium adsorptive potential of an exopolysaccharide (EPS) released during the growth of an indigenous cyanobacterium, Oscillatoria trichoides Szafer, were investigated in a laboratory‐scale study. The results showed that, of the total EPS produced, 410.53 milligrams/gram (mg g^?1) were released polysaccharides (RPS) and 11.36 mg g^?1 were capsular polysaccharides (CPS). The sorption of hexavalent chromium (Cr⁶⁺) by the RPS achieved a maximum amount of metal removal (q_max) value of 76.92 mg g^?1 of polysaccharide dry weight. The highest coefficient of determination (0.9742) for the Langmuir adsorption model indicates best fitness of the model in explaining the sorption as a unilayer process. Equilibrium studies indicated that 30 to 40 milligrams per liter initial chromium concentration and a pH of 2 were optimal for biosorption of chromium by the RPS. Scanning electron microscopy with energy‐dispersive X‐ray spectroscopy analysis of Cr⁶⁺‐treated RPS showed the presence of 3.76% bound chromium. Compositional analysis of the EPS showed the presence of carbohydrates, proteins, pyruvic acid, and hexosamines. High‐performance liquid chromatography analysis demonstrated the presence of hexoses, as neutral sugars and glucuronic acid as an acidic sugar. The presence of carboxylic groups was also detected by infrared spectroscopy. The presence of these chemical constituents may serve as binding sites for the metal ions; therefore, the RPS of this species appears to be a promising biosorbent for Cr⁶⁺.     

Modification of Thermo-Mechanical Properties of Recycled PET by Vinyl Acetate (VAc) Monomer Grafting Using Gamma Irradiation

Vinyl acetate (VAc) monomer of different percentage was grafted onto the recycled polyethylene terephthalate (r-PET) films using gamma irradiation. The properties of these modified films were characterized by Fourier transform infrared spectroscopy (FTIR), mechanical properties testing (Tensile strength, Elongation at break), dynamic mechanical analysis (DMA) and thermo-gravimetric analysis (TGA). The Tensile Strength (TS) of the modified PET film increased by 132.25?% to the highest value of 50.12 MPa at 15% VAc monomer concentration at 3 kGy gamma dose, while the elongation at break (EB) decreased by 31.83?%. FTIR was used to investigate the molecular interaction of the modified films. TGA revealed that curve of the modified PET film shifted toward higher temperature region by 95?°C, which is very close to that of PET film made from virgin flakes. The results indicate that modified PET films of better mechanical and thermal properties were successfully prepared using VAc monomer grafting by gamma irradiation technique.     

Factors Affecting Predator-Prey Distribution in a Protected Area,Tehran, Iran (a Case with Wolves and Wild Sheep)

We tried to model habitat suitability of two prey and predator species including wild sheep (Ovis orientalis) and wolf (Canis lupus) in Varjin protected area located in northern east of Tehran using a presence only method, maximum entropy (MaxEnt). Totally 11 environmental variables were measured in the species presence points which can be classified in three groups including topographical, vegetation and distal variables. Resulted maps indicated that habitat variables such as slope (ranging from 35 to 40 percent) and elevation (lower than 1700 meters above sea level) are both institute those factors which mostly affect studied prey and predator habitat use. Our results regarding prey and predator geographical range of used habitat indicated that wolves cover most area than wild sheep which show more dispersed habitat resources for the prey species. ENMTools test revealed that wolf’s niche breadth is more than twice as much as wild sheep’s. Wild sheep in Varjin protected area has a relatively narrow geographical extent and shows a tendency to marginal habitats while wolves cover obviously more areas which denotes its high mobility and low dependency to specific habitats.     

Modeling the decline of labor-sharing in the semi-desert region of Chile

Regional Environmental Change - The rapid environmental changes currently underway in many dry regions of the world, and the deep uncertainty about their consequences, underscore a critical...     

The socio-economic vulnerability of the Australian east coast grazing sector to the impacts of climate change

Regional Environmental Change - Research that projects biophysical changes under climate change is more advanced than research that projects socio-economic changes. There is a need in adaptation...     

Transfer of Graphene CVD to Surface of Low Density Polyethylene (LDPE) and Poly(butylene adipate-co-terephthalate) (PBAT) Films: Effect on Biodegradation Process

Here, the influence of graphene as a coating on the biodegradation process for two different polymers is investigated, poly(butylene adipate-co-terephthalate) (PBAT) (biodegradable) and low-density polyethylene (LDPE) (non-biodegradable). Chemical vapor deposition graphene was transferred to the surface of two types of polymers using the Direct Dry Transfer technique. Polymer films, coated and uncoated with graphene, were buried in a maturated soil for up to 180 days. The films were analyzed before and after exposure to microorganisms in order to obtain information about the integrity of the graphene (Raman Spectroscopy), the biodegradation mechanism of the polymer (molecular weight and loss of weight), and surface changes of the films (atomic force microscopy and contact angle). The results prove that the graphene coating acted as a material to control the biodegradation process the PBAT underwent, while the LDPE covered by graphene only had changes in the surface properties of the film due to the accumulation of solid particles. Polymer films coated with graphene may allow the production of a material that can control the microbiological degradation, opening new possibilities in biodegradable polymer packaging. Regarding the possibility of graphene functionalization, the coating can also be selective for specific microorganisms attached to the surface.     

The spillover of race and racial attitudes into public opinion about climate change

The relationship between racial attitudes and public opinion about climate change is examined. Public opinion data from Pew and American National Election Studies surveys are used to show that racial identification and prejudices are increasingly correlated with opinions about climate change during the Obama presidency. Results show that racial identification became a significant predictor of climate change concern following Obama’s election in 2008, and that high levels of racial resentment are strongly correlated with reduced agreement with the scientific consensus on climate change. These results offer evidence for an effect termed the spillover of racialization. This helps further explain why the public remains so polarized on climate change, given the extent to which racial grievances and identities have become entangled with elite communication about climate change and its related policies today.     

Preparation of Porous Nanofibers from Electrospun Polyacrylonitrile/Polyvinylidene Fluoride Composite Nanofibers by Inexpensive Salt Using for Dye Adsorption

The high surface area of porous nanofibers enhances their performance for many applications. The present study investigated electrospinning and dye adsorption properties of polymeric nanofibers which were porous by various types of salts. The salt/polyacrylonitrile/polyvinylidene fluoride composite nanofibers were electrospun, and the inexpensive salts such as sodium chloride (NaCl), sodium bicarbonate (NaHCO₃), or calcium chloride (CaCl₂) was used to manufacture the porous fibers. Subsequently, the salt was removed by a selective dissolution, and salt extraction of nanofibers was performed with the solution of hydrochloric acid (10 wt%). Salt/PVDF/PAN and porous PVDF/PAN composite nanofibers have been applied to dye adsorption of solution. The characteristics of nanofibers were studied by Fourier transform infrared microscopy (FTIR) and scanning electron microscopy (SEM) analysis. FTIR showed that the salt was extracted from PVDF/PAN nanofibers successfully, and SEM indicated that many pores were aligned with the nanofibers. The adsorption capacity of salt nanofibers webs and porous nanofibers webs for Basic Blue 41 were compared with each other, and porous fibers were obtained from NaHCO₃ having the highest dye adsorption value. Adsorption of dyes follows the Langmuir isotherm and pseudo-second order kinetics.